Session 5
CHAIR: Jasna Vuković
10:00-10:15 CET
Tomislav Brenko (1), Tena Karavidović (2), Sibila Borojević Šoštarić (1) & Tajana Sekelj Ivančan (2) - Mineralogy and geochemistry of iron slags towards their provenance studies in Podravina region, NE Croatia(1) Faculty of Mining, Geology and Petroleum Engineering, University of Zagreb, Croatia
(2) Institute of archaeology, Zagreb, Croatia
Archaeological excavation and field surveys in the Podravina region led to the discovery of numerous sites with traces of iron ore smelting and processing of the bloom that were dated to the Late Antique and Early Middle Ages. The discovered slag can be divided into two main categories: smelting slag (furnace bottom and tap slag) and primary smithing slag. The main focus of this study is 33 samples of tap slags and furnace bottom slags from archaeological sites Hlebine-Velike Hlebine, Virje-Sušine, and Virje-Volarski Breg and their provenance towards locally discovered bog iron ores using mineralogical and geochemical analyses. X-ray diffraction confirmed fayalite as the main mineral phase, with occurrences of other Fe minerals, such as wüstite and magnetite. Geochemical analysis confirmed high Fe contents ranging between 52.30 and 66.46 wt. %, typical values for iron bloomery. Previous studies confirmed bog iron ore occurrences in the study area, both in archaeological as well as geological context. Therefore, provenance studies were carried using major, trace, and rare earth elements. Non-Reducible components ratios and principal component analysis revealed some differentiation between the samples from different archaeological sites, mostly due to aluminum contents. The geochemical signature of both bog iron ores and iron slags was constructed using 26 major, trace, and rare earth elements. Both ore and slag signatures are characterized by similar shapes, peaks, and patterns, implying a genetic connection between the bog iron ores and iron slags in the Podravina region.
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10:20-10:35 CET
Ilaria Calgaro (1), Umberto Veronesi (1), Antonina Ermolaeva (2) & Miljana Radivojević (1) - Copper production and technology at Mid-Late Bronze Age Taldysai (central Kazakhstan): its place in the wider Eurasian metalmaking framework(1) Institute of Archaeology (UCL), London, UK
(2) Institute of Archaeology named after A.Ch. Margulan, Almaty, Kazakhstan
Second millennium BC Eurasian copper extractive metallurgy is widely assumed as large-scale and standardised, with its highest technological peak reached during the Mid-Late Bronze Age. Present-day Kazakhstan and Southern Urals host among the richest polymetallic ore deposits of Eurasia, massively exploited since the Early Bronze Age by the Steppe pastoralist communities. The metallurgical workshop of Taldysai in the steppes of central Kazakhstan was one of these production centres and represents the focus of this study. Extensive evidence of metalmaking has been unearthed at this site, including complex smelting furnaces, production debris, mining and beneficiation tools and finished metal artefacts.
Out of these, seven copper smelting slags were chemically and microstructurally analysed by Optical and Energy Dispersive Scanning Electron Microscope and provided a first insight into the multi-step metallurgical chaîne opératoire carried out onsite. Then, in order to test the estimated uniformity of Mid-Late Bronze Age copper extractive metallurgy, data collected from Taldysai were integrated with a comparative reference database of thirteen coeval metalmaking sites located between the Eastern Alps and Central China and analysed through multivariate statistics in form of principal component analysis (PCA) and ternary diagrams.
Overall, this study sheds light on the metallurgical process carried out at Taldysai and presents preliminary elements to fit in the wider second millennium BC narrative. Results highlight how specific choices dictated by local/regional-scale inventiveness, the exploitation of different mineral ores and the technological solutions adopted by Bronze Age metalsmiths determined variations in smelting steps, technological parameters and efficiency of copper production across Eurasia.
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10:40-10:55 CET
Tena Karavidović & Tajana Sekelj Ivančan - Interpreting the archaeological record of iron production sites: a multi-method approachInstitute of Archaeology, Zagreb, Croatia
Iron production is a multi-step process that involves raw material exploitation (primarily ore and wood) and preparation (ore dressing and charcoal production), smelting, and primary and secondary smithing. Defining the traces of activities related to iron production on archaeological sites as well as reconstructing the past technological solutions is a complex process. It can involve the comparison of the results gained by different methods of archaeological research: i.e. chronological and spatial analysis of stratigraphic sequence and related artefacts; macroscopic, mineralogical, and chemical analysis of iron production waste; experimental testing of different phases of the production process; which result in various types of datasets. Combining the results of the aforementioned methods, applied on archaeological remains from several sites with traces of bloomery and related activities and dated to Late Antiquity and Early Middle Ages (Velike Hlebine, Dedanovice, Volarski breg, and Sušine), allows the development of a methodological framework for interpreting the archaeological record of iron production sites.
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11:00-11:15 CET
Julia Fileš Kramberger (1) & Zorana Kovačević (2) - SEM in Archaeological Textile Research(1) Department of Archaeology, Faculty of Humanities and Social Sciences, University of Zagreb, Croatia
(2) Department for Textile Chemistry and Ecology, Faculty of Textile Technology, University of Zagreb, Croatia
Scanning Electron Microscopy (SEM) is a very useful method for textile fibre identification and morphology analysis. It can be used in a broad range of diverse scientific research fields. Archaeological textile, as one of them, proved to be a specific challenge because of sample size, its age and state of preservation. However, like other analytical methods, the interpretation of results is closely related to the sample preparation for SEM investigation.
In this paper, work on several textile fragments from the Early Iron Age period will be presented. They were all found on fragments of iron horse gear, within the burial chamber in Tumulus 6 at the site of Kaptol-Gradac in the Požega valley, and dated to the Ha C1 period. The iron finds were previously consolidated for conservation purposes. During conservation, mineralized textile remains were discovered, which were photographed and analysed using nondestructive digital microscopy to determine the weave type and density, thread thickness and twist direction. Further on, in order to identify the fibres, samples were taken for SEM analysis. Above all, the goal was to analyse such samples in order to develop a new methodology for SEM analysis of archaeological textile in our further research.
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11:20-11:35 CET
Aleksandra Cetwińska (1), Ewa Wagner-Wysiecka (2), Katarzyna Kwiatkowska (3) & Dariusz Manasterski (4) - Origin versus style. An interdisciplinary study of amber ornaments from NE Poland(1) Antiquity of Southeastern Europe Research Centre University of Warsaw, Poland
(2) Faculty of Chemistry, Department of Chemistry and Technology of Functional Materials, Gdańsk University of Technology, Poland
(3) Polish Academy of Sciences Museum of the Earth in Warsaw, Poland
(4) Faculty of Archaeology University of Warsaw, Poland
Various types of fossil resins can be found in the Baltic Sea, the most famous of which is succinite. It is the Baltic amber, which is still used for the production of amber items. It was used also in the late Neolithic period in north-eastern Poland when the presence of numerous amber workshops located around the Gdańsk Bay and the Żuławy Wiślane region has been recorded. Although amber seemed to be an easily accessible raw material in this area, so far only a few sites with such products have been discovered there. These include Ząbie X and Supraśl 3, where some adornments with stylistic features never recorded in Poland before were discovered. Due to the exotic nature of the artefacts, they were subjected to macro-, microscopic analysis and FTIR spectroscopy. The research showed not only the Western European provenance of the manufacturers but also revealed that they used local amber. Interestingly, apart from succinite, the presence of other resins - gedanite and gedano-succinite - was also detected. This is the first time such discovery was made.
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BREAK: 11:40-12:00 CET
Session 6
CHAIR: Ivana Ožanić Roguljić
12:00-12:15 CET
Andreja Kudelić (1), Dinko Tresić Pavičić (2), Natali Neral (1), Mia Marijan (3) & Ana Maričić (4) - Research on Bronze Age pottery traditions – Conceptual approach(1) Institute of Archaeology, Zagreb, Croatia
(2) Kaducej d.o.o., Split, Croatia
(3) Pod kosom 47, Split, Croatia
(4) Department of Mineralogy, Petrology and Mineral Resources; Faculty of Mining Geology and Petroleum Engineering, University of Zagreb, Croatia
The tradition of studying archaeological ceramics in Croatia is deeply rooted in the culture-historical approach, especially when it comes to prehistoric pottery, which represents most of the archaeological record on prehistoric societies. However, turning the approach, by studying pottery throughout its lifecycle from raw material selection, different stages of production, to distribution and use, can provide valuable research contributions in a topic still not fully explored. Over the next five years, extended research on Bronze Age (2400-800 BC) pottery traditions on the territory of Croatia will be conducted. The paper will present the project concept and methodology approach. A prerequisite for the selection of archaeological material is a well-established stratigraphic and chronological context and in the initial phase, the ceramics will be classified with the focus on typology and style aiming at cultural and temporal determination. In addition, through a macroscopic examination of the pottery, an analysis of manufacturing techniques and vessel function will be carried out. A large part of the research protocol will be focused on the analysis of archaeological ceramics and pottery raw materials using various analytical techniques (ceramic petrography, XRD, FTIR and geochemistry).
All the information gathered will form a large set of data, that represent the basis on which the properties of production, distribution, and use through specific research questions, will be evaluated, and analysed. Therefore, the correlation of different interdisciplinary data sets, quantification methods, and digitalization of such data, currently presents the biggest challenge. In that sense, awareness of the advantages but also limitations of analytical methods and a well-formed theoretical framework, research questions, and hypotheses are key parameters of an optimal methodological approach.
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12:20-12:35 CET
Anđa Petrović (1,2), Cristina Lemorini (1) & Stella Nunziante-Cesaro (3) - Reference collection as key element of use-wear and residue analysis of chipped stone assemblages: study of Iron Gates region (Serbia)(1) Sapienza University of Rome, Laboratory of Technological and Functional Analyses of Prehistoric Artefacts, Rome, Italy
(2) Department of Archaeology, Faculty of Philosophy, University of Belgrade, Serbia
(3) SMATCH Italia (Scientific Methodologies Applied to Cultural Heritage), Rome, Italy
The experimental procedure has been one of the fundamental methods in the use-wear and residue studies of the chipped stone assemblages for decades. This type of approach is considered to have an important role in the cognitive development of the functional analysis, more specifically in the educational component. The paper aims to examine the impact experiments have in the case of addressing specific research questions and hypotheses.
The closed eco-niche like Iron Gates revealed the economical and social aspects of its inhabitants during the Late Glacial and Early Holocene. Everyday tasks and activities are known in recent years, when the particular study, targeting the function of the chipped stone tools from Lepenski Vir, Padina and Vlasac, was conducted. The research which consisted of 51 experiments resulted in the first reference collection in the region, which included both formal and problem-oriented trials.
The idea of the study is to address the necessity and the wide application of the experimental approach represented by simple activities, connected to the broad chronological span, as cutting, scraping, engraving performed on the materials available in Late Mesolithic and Early Neolithic, as hide, bone, antler, or wood. Additionally, a number of problem-oriented experiments, as fish processing, or the use of tools after thermal stress were done to answer the particular research questions connected to the lifestyle of both local and incomer groups in the Transitional period.
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12:40-12:55 CET
Nikola Marković (1), Boban Tripković (2), Marko Porčić (2), Ana Tripković (2) & Jasna Vuković (2) - Preliminary X-Ray Fluorescence Analysis of Early Eneolithic Pottery: Šanac-Izba near Lipolist (Western Serbia)(1) Vukasovićeva 19a, 11000 Belgrade, Serbia
(2) Department of Archaeology, Faculty of Philosophy, University of Belgrade, Serbia
Šanac-Izba near Lipolist is an Early Eneolithic site located in western Serbia. It is a small site of only 40 m in extent surrounded by a wide ditch. The archaeological traces of several pits (pits 1-4) and one burnt building were revealed in 2013. The building and pit 4 can be generally dated to the Early Eneolithic, which correspond to the late 5th millennium BC of the regional chronology. The other pits were certainly dug later and filled up with redeposited cultural material by natural processes. Pottery collected at the site represents a mix of cultural styles originating in the central Balkans and south Pannonian Basin. Diagnostic ceramic fragments were sampled preliminarily and analyzed to answer two research questions: 1) Is there a difference in the elemental composition of certain pottery types; 2) Can we observe a chemical and technological variability in the pottery belonging to different cultural traditions? The 41 powdered samples were taken from typologically defined pottery fragments, and the sample covers all features and many units. The elemental composition was obtained by the XRF instrumental method.
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13:00-13:15 CET
Aleksandra Cetwińska (1), Grzegorz Koczan (2), Maciej Sadło (3) & Dariusz Manasterski (3) - Potential of using reed arrow shafts hidden in their spine-force value(1) Antiquity of Southeastern Europe Research Centre University of Warsaw, Poland
(2) Institute of Wood Sciences and Furniture, Poland
(3) Faculty of Archaeology University of Warsaw, Poland
Grooved stones are a common find in the archaeological record. These are small stone or clay artefacts varying in shape, quality, and decoration, with transverse grooves. These items are associated with at least sixty cultures ranging from the Mesolithic/Proto-Neolithic to the Bronze Age and occur over a vast territory which includes the Near East, northeastern and southern African coast, steppe, forest-steppe, and semi-desert regions of Eurasia from northeastern Europe and Moldavia to Mongolia. It is believed that they were used to straighten reed arrows. While the occurrence of such arrow shafts is confirmed in the literature, no studies have ever been conducted to verify the potential for their use. We present our experimental conclusions based on the preliminary measurement of reed spin values.
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BREAK: 13:20-14:00 CET
Session 7
CHAIR: Jacqueline Balen
14:00-14:15 CET
Ines Krajcar Bronić (1), Ivor Karavanić (2), Andreja Sironić (1), Nikola Vukosavljević (2), Marko Banda (2) & Fred Smith (3, 4) - Radiocarbon dating of the Middle Paleolithic animal bones from two caves, Croatia(1) Ruđer Bošković Institute, Zagreb, Croatia
(2) Department of Archaeology, Faculty of Humanities and Social Sciences, University of Zagreb, Croatia
(3) Department of Sociology and Anthropology, Illinois State University, Normal, USA
(4) Department of Anthropology, University of Colorado, Boulder, USA
The aim of the project „Last Neandertals at the Crossroads of Central Europe and the Mediterranean – NECEM“ (financed by Croatian Science Foundation, HRZZ-IP-2019-04-6649) is to gain new data on the adaptations of late Neandertals in today’s Croatia by interdisciplinary methods. Radiocarbon dating method gives a chronological framework providing the samples are not older than about 50000 years.
A total of 16 bone samples from two caves, Vindija (Donja Voća, NW Croatia) and Mujina Pećina cave (Plano, near Kaštela, Dalmatia), were selected for radiocarbon AMS dating at the Ruđer Bošković Institute (RBI) laboratory. Collagen extraction yielded >1% of collagen for 10 samples. From six samples the collagen yield was lower than 0.5 % and those bones could have not been dated since the low yield (<1%) may produce an underestimated radiocarbon age. For comparison, 12 bone samples were sent to Oxford Radiocarbon Accelerator Unit (ORAU) for radiocarbon dating with an additional step of ultrafiltration (UF) to select collagen fraction having molecules larger than 30 kDa. Four of them could not have been dated due to low collagen yield (<1 ‰), five were dated in spite of low yield, and only three them successfully dated. the results 13c values bone samples showed same range both rbi orau laboratories, between -18.3 ‰ -21.8 ‰, which are typical for collagen. radiocarbon conventional ages these limited number comparable. much more dating old bones necessary to obtain reliable results.
The preliminary results presented here point to the possible obstacles in radiocarbon dating of late Middle Paleolithic samples: bones are not well preserved, yield of collagen is often low, and the age is close to the limit of the radiocarbon method.
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14:20-14:35 CET
Miroslav Marić (1), Jelena Bulatović (2) & Nemanja Marković (3) - Regional Absolute Chronologies of the Late Neolithic in Serbia(1) Institute for Balkan Studies, Serbian Academy of Science and Arts, Belgrade, Serbia
(2) Laboratory for Bioarchaeology, Faculty of Philosophy, University of Belgrade, Serbia
(3) Institute of Archaeology, Belgrade, Serbia
In 2020, despite the ongoing Covid19 epidemic, a project "Regional Absolute Chronologies of the Late Neolithic in Serbia" started, aimed at detailed radiocarbon dating of the Late Neolithic phenomenon known as the "Vinča culture" in the traditional archaeological sense of the term. The project, combining radiocarbon dating technology and statistical seriation of ceramic assemblages from individual sites is an attempt to further narrow the chronological margins of the 800-1000 year long development that occupies large parts of the central Balkans and south edge of the Carpathian basin between the 54th and 45th century BC.
Using archival collections from regional museums across Serbia, the project established new chronological "beacons" that can be used to relate chronological information for surrounding sites to be excavated in future. A year into the project, here we present the first results from several sites in north and central Serbia and rate the current state of knowledge in the field and the region.
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14:40-14:55 CET
Andreja Sironić (1), Žana Matulić Bilač (2), Barbara Španjol-Pandelo (3) & Ines Krajcar Bronić (1) - Dating wooden artefacts treated with resins(1) Ruđer Bošković Institute, Zagreb, Croatia
(2) Croatian Conservation Institute, Zagreb, Croatia
(3) Faculty of Art and Sciences, University of Rijeka, Croatia
The wooden Romanesque Crucifix from Collection of Sacral Art in Poreč has been restored 1994-1999 in Conservation department of Split when the multidisciplinary research detected that original Christus triumphans has been transformed into Cristus dolorens in the early 18th century. Project Ars lignea: the Woodcarving Art Heritage of the North Adriatic from 1300 until 1600 (the University of Rijeka) involved the new possibility of radiocarbon dating of original wood (poplar). A sample was taken from the Christ's corpus.
The procedure of radiocarbon dating of wood, performed at the Zagreb Radiocarbon Laboratory, usually involves the so-called A-B-A or acid-base-acid chemical preclearing. The sample was inspected by microscope in order to remove larger foreign material, washed with ultrapure water and then subsequently treated by HCl, NaOH solution and again by HCl. This procedure removes carbonates and large organic molecules present in soil: fulvic and humic acids. However, it does not remove organic varnishes or other synthetic materials that might have been applied to the artefact. Since these coatings contain organic molecules, dating may lead to erroneous dates. When the coating is obvious, or there are indications that the artefact had been treated with synthetic coatings, a series of organic solvents is used for washing the sample before A-B-A procedure. The washing starts with a non-polar solvent, followed by a solvent with higher polarity and eventually ends with the most polar solvent, i.e. water.
Here we present a case of a wood sample taken from the Christus dolorens that did not seem to have been treated with coatings. However, its 14C activity and δ13C value proved it was treated with resins of fossil origin. In repeated measurements, it was proved that the procedure of solvent cleaning we use is efficient in removing the coating contaminates.
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15:00-15:15 CET
Dinko Tresić Pavičić (1), Željka Bedić (2) & Filomena Sirovica (3) - System for Recording and Analyzing Articulated Human Skeletal Remains(1) Kaducej d.o.o., Split, Croatia
(2) Anthropological Centre, Croatian Academy of Sciences and Arts, Zagreb, Croatia
(3) Archaeological Museum in Zagreb, Croatia
Bioarchaeological analyses have the potential to generate a large amount of various data that require an efficient system of collection, storage, access and processing. In the scope of the Croatian Science Foundation project "milOrd: Development and Heritage of the Military Orders in Croatia" (IP-2019-04-5513), which is, among other things, focused on the analysis of large amounts of human osteological material found during archaeological excavations, a system for managing and processing of data collected by bioarchaeological analysis has been developed. The authors will present an easy-to-use system for recording and analysing articulated human skeletal remains in a digital environment using predesigned forms and tables. The main goal of this procedure is to improve the current recording system, i.e. to enable simpler and faster access to recorded data through the use of relatively simple and well-known software, to speed up and simplify the bioarchaeological analysis, and to enable compatibility with other archaeological field data within the database.
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15:30 CET
Closing